Kum 1863 hma lam khan silicon-miten an hriat leh an hman thin compound awmna zawng zawng chu inorganic silicon compound an ni a, chutah chuan natural silicon-Tunlai thil siam chhuah, ceramics, cement, leh glass-a inthlak danglam te pawh a tel a ni. Kum 1863 khan French chemists C. Feidedel leh JM raft te chuan ethyl zinc leh silicon tetrafluoride te chu sealed tube-a an inrem avangin tetraethyl silane an siam chhuak a. Historic-a organosilicon compound hmasa ber a ni. Hei hian organosilicon chemistry a bul tanna a ni bawk.
Chuta tang chuan chemists te chuan organosilicon compound thar an siam chhunzawm zel a. Chumi zingah chuan sawi tur a awm a, chu chu A. Lamenberg a ni a, chu chuan ethyl orthosilicate hmangin silicon tetrachloride aiah leh alkyl zinc hmanga organosilicon compounds mono -, II -, leh III silicon functionals, leh a.polis te chu a hmu chhuak a, chu chuan first all{{5} through anane, CAWLINE, TETRAWANE, TETRAWANE, TETRAWANE, TETRAWANE, TETRAWANE, CAWHERTZ te chu a siam chhuak a ni. tilet. Kum 1903 thlenga kum 40 chhung khan silicone hmasawnna tichaktu tak tak technology lama hlawhtlinna siam chhuah a ni lo nain, chemists-te chuan he hun chhung hian hmahruaitu hna tam tak an thawk a ni. Chuvangin, he stage hi silicone din hun lai anga ngaih theih a ni.
British chemist lar tak fskipping hi Organosilicon Chemistry dintu anga ngaih a ni. Kum 1898 atanga 1944 thleng khan he field-ah hian zirchianna zau tak leh - thuk tak a nei a, Journal of the Chemical Society of the United Kingdom-ah chuan paper inzawm 51 a tichhuak chhunzawm zel a ni.
Kum 1904 khan W leh German chemist Dithey chuan independent takin organosilicon compound te chu grignard reaction hmangin an siam chhuak thei tih an hmuchhuak a. Hetiang method hi a hmaa metal-organic synthesis methods te aiin nasa takin a lo tha chho a, hei hi a hman awlsam em em avang te, a yield sang, a hmanna hmun zau tak leh a himna a sang em em vang a ni. Hetiang hmang hian organosilicon compound chi hrang hrang silicon functionality hrang hrang nei te chu synthesize theih a ni .
Kip-Ping hian he method hmang hian well-defined organosilicon compound tam tak a siam chhuak a. Hetiang hmanrua hi nakin lawkah chuan organosilicon industry dinna bulpui ber a lo ni ta a, tunlai Organosilicon siamna atana synthesis method pawimawh ber pawl a la ni reng a ni. RMGCL+SICL- RSICL:+RSICL+R:SIC1+ RSI +MGCL,(2.3)Kipping Synthesized organochlorosilanes chu grignard reagent method hmangin hydrolyzed theih a nih thu an hmuchhuak a, chu chu silanol siam theih a ni. Chutih rual chuan silanediol leh siltriol te pawhin intermolecular condensation an paltlang belh thei a, polymer an siam thei tih a hmuchhuak bawk. Mahse, organic chemist a nih angin he reaction hi a ngaihven lo tak zet a, heng polymer products te pawh hi a huat em em a ni. Chuvangin, a zir chiang lo. Hemi chungchangah hian Dilthey hian hna awmze nei tak an thawk tak zet a ni: hexaphenylcyclorisiloxane a hmuh theih nan diphenylsilanediol a condensed a. Hei hi cyclic polysiloxane compound history-a report hmasak ber a ni. Linear silicon-oxane siamna kawnga hmahruaitu a ni a, a lo chhuahna hian organosilicon polymer hmasawnna kawngah pawh hmun tha tak a chang a ni.
Kum 1904 atanga 1937 thleng khan scientist te chuan organosilicon compound awlsam tak tak tam tak an siam chhuak mai bakah cyclic leh linear polysiloxysaccharides an nei bawk. Chu bakah, a.stock hian fundamental research-ah silanhydride tam tak a hmuchhuak a, asymmetric silicon atom compounds siam chhuah tan a ni bawk. Kum sawmthum kalta chhung khan Organosilicon chemistry tan chuan hmasawnna hun a ni.
Kum 1930 chho hnu lamah chuan chemists te chuan high-molecular organosilicon compounds hman dan tur an hre tan ta a. Hemi lama zirchiangtu hmasa berte chu United States-a Corning Glass Company-a JFHYDE, WJ Petnode leh Egrohow-a General Electric (GE) te, United States-a Egrohow, leh Soviet Union hlui Andrianov leh Bndolgov, R. Miller-a te zinga mi, etc. te an ni.
Hyde hi Kipping-a ngaihdan nen a inkalh takin, organosilicon chemistry leh polymer chemistry inzawmkhawm hmasa ber a ni. A kaihhruaina hnuaiah Corning Inc. chuan electrical insulating glass puan atan silicone resins, coatings, impregnating agents leh polyorganosiloxane product dang tam tak a siam chhuak a ni. Hetihlai hian United States-a dowchemicals te pawhin polyorganosiloxanes siam chhuah dan zirchianna an tan a, kum 1942 khan dimethyl silicone oil leh methyl phenyl silicone resin te tan pilot plant an din a, chutih lai chuan organochlorosilane monomers te chu grignard method hmanga siam an ni ber a, chuvangin monomers te chu an lo awm ta a ni. Kum 1940 khan Rochow chuan methylsilane "direct synthesis method" a siam chhuak a, patent a dil a. Hetiang method hian solvent a hmang lo. Gas-solid phase reaction a ni a, chloromethane chu copper catalyst awmna silicon powder-ah direct-in an dah lut a ni (Equation 2.4). Hetih lai tak hian German chemist Muller pawhin hetiang patent hi a dil ve bawk a, mahse a ngaih pawimawh hun tur chu Rochow’s aiin thla 9 hnuah a ni. He thawhhlawk tak hian silicone siamna kawngah nasa takin revolution a siam a, silicone industry hmasawnna tur a tichak bawk.
Kum 1943 khan Dow Chemical Company leh Corning Inc. te chuan khawvel an din dun a-Silicone professional company hmingthang tak - Dow Corning Corporation an din a, chu kum vek chuan Mdand, Michigan, USA-ah polyorganosiloxanes siamna tur factory an siam bawk. Company chuan rei lo teah DC#4 ignition sealing material chu an siam a, high-altitude aircraft-ah hlawhtling takin an hmang ta a ni. A hnuah chuan company chuan silicone resin chi hrang hrang, coatings, shockproof oil, lubricating oil, defoamers leh thil dang dang an siam chhuak leh a. Kum 1947 khan General Electric Company pawhin organosilicon division an din a, chu chuan direct method hmangin organosilicon gas a siam a, polysiloxane products a siam chhuak bawk. General Electric Company-in a siam chhuah technology chu a hnu lama silicone factory-te chuan an hmang ta a ni.
Soviet Union hluiah khan silicone polymers lama zirchianna chu a langsar hle a, a bik takin Andrianov-a chuan a ti langsar hle a ni. Polysiloxane polymers-a hna tam tak a thawh bakah practical application value nei organosilicon polymer tam tak a siam bakah, element dang boron, aluminum, titanium, tin leh phosphorus te pawh polysiloxane structure-ah siam danglamna atan a rawn luhtir bawk. Silazane hi waterproof coating atan hmang hmasa ber a ni bawk.
Indopui II-na a tawp hnuah, sipai thil siam chhuahnaah silicone thil siam hlawhtling tak a nih avangin, silicone industry chu a lo thang chak hle a, a siam chhuah zawng zawng chu regularized path-ah a kal vek a ni. Kum 1950 chhoah khan ram hrang hrangah silicone product siamtu company te chu a hnungzuiin an din a. Silicone polymer material chi hrang hrang, silicone rubber (high-Temperature curing rubber, room temperature vulcanizing rubber, transparent silicone rubber, oil{4}}resistant fluorosilicone rubber, etc.) ang chi, diffusion pump oil, laminating resin, silicone emulsion, silicone surflation, silicone ablation, silicone agent, silicone agent, silicone agent, silicone, silicone agent, silicone agents. A hnungzuiin a rawn chhuak a.
Kum 1938 leh 1965 inkar khan theory leh application-ah pawh; Organosilicon chemistry hian monomer leh polymer-ah pawh hma a sawn chak hle. Hetah hian a pawimawh ber berte chu: silicylation reaction, hydrosilylation reaction, photoactive organosilicon compounds zirchianna, carbon functional group awmna organosilicon compound siam, reaction mechanism zawng chhuah, polymerization method siam that, leh silicone rubber, leh coupling agents te, silicone rubber, leh coupling agents te lo chhuahna a lo chhuahna tur a awm lo.
Kum 1965 atang khan hlawhtlinna awmsa te tihngheh, tihhmasawn, tihchangtlun leh hman tangkai bakah hian mipui pawhin organosilicon chemistry field thar lam an pan ta a ni. Chung zingah chuan, a langsar zualte chu: Organosilicon stereochemistry, physiological activity nei organosilicon compound, cyclic leh linear polysilanes, silicon- reaction intermediate hrang hrang awmna, silicon-a unsaturated bond compounds, silicon awmna ternary ring, siliconine blocks, polyasison te Sesquiloxanes, silicon-Dendritic leh hyperbranched polymer compounds, etc. Containing silicone industry-ah chuan silicone monomer leh polymer siam chhuahna scale a zau zel a, production technology pawh a ṭha chho zel a, production cost pawh a tlahniam zel bawk. Hei hian silicone products te chu a ti inelna a tichangtlung zawk a ni. Multi-functional leh high-performance silicone products, medical, conductive leh thermal conductive polysiloxanes te siam chhunzawm zel chuan an application scope chu a tizau zel a ni. Silicone thil siamte chu ram economy field hrang hrangah a luhchilh reng a, chu chu a chi hrang hrangah a lut a, chu chu silicone oil, silicone rubber, silicone resin, leh silane coupling agents te a ni.